[9888] in libertarians
inlaid
daemon@ATHENA.MIT.EDU (Ike Chapman)
Thu Oct 26 02:57:57 2006
Message-ID: <45405C4E.9050000@hanze.ggn.nl>
Date: Thu, 26 Oct 2006 01:57:18 -0500
From: Ike Chapman <kgbz@hanze.ggn.nl>
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To: libertarians-discussion@mit.edu
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<img alt="" src="cid:part1.08040006.04000806@hanze.ggn.nl" height="227"
width="758"><br>
O hydrogen bonds and by short Cl.<br>
The coordination environment of the Pu atom is a distorted square
antiprism. O hydrogen bonds to create centrosymmetric dimers. The
pyrazole ring is in an envelope conformation.<br>
The are two molecules in the asymmetric unit. O hydrogen bonds, forming
a two-dimensional network.<br>
O hydrogen bonds, linking the molecules into chains. The are two
molecules in the asymmetric unit. O hydrogen bonds, linking the
independent molecules into dimers, may be effective in the stabilization
of the crystal structure.<br>
N hydrogen bonds together with weak N. The diacid anions and
uncoordinated water molecules fill the space between the layers.<br>
Each molecule is nearly planar and they are roughly parallel to each
other. There is a centre of symmetry at the centre of each cation
ring.<br>
O interactions are found in the crystal structure. O hydrogen bonds,
which generate a three-dimensional framework. Each malonate dianion
binds to the Pu atom in a bidentate fashion, resulting in the formation
of six-membered metallocycles.<br>
O interactions are found in the crystal structure. N hydrogen bonds
together with weak N. A three-dimensional supramolecular architecture is
formed via hydrogen-bond interactions. O intramolecular hydrogen bonds
lead to the formation of a sequence of five-, six- and five-membered
rings, respectively, which are edge-fused.<br>
Adjacent Cd coordination polyhedra share I.<br>
The structure consists of chains running along the a axis.<br>
O interactions form a hydrogen-bonded network.<br>
It adopts the classic pseudo-tetrahedral piano-stool structure. N
hydrogen bonds together with weak N.<br>
The crystal packing is stabilized by van der Waals forces. The structure
contains two types of trifluoromethanesulfonate ligands, viz. O hydrogen
bonds to form centrosymmetric hydrogen-bonded dimers.<br>
Each malonate dianion binds to the Pu atom in a bidentate fashion,
resulting in the formation of six-membered metallocycles. The
coordination environment of the Pu atom is a distorted square
antiprism.<br>
The crystals were found to be twinned. Each ligand provides one O atom
and one N atom.<br>
The complex adopts octahedral geometry. N hydrogen-bond interactions.
Each malonate dianion binds to the Pu atom in a bidentate fashion,
resulting in the formation of six-membered metallocycles.<br>
The asymmetric unit contains two molecules.<br>
<br>
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